N-Heterocyclic carbenes as ligands in palladium-catalyzed Tsuji–Trost allylic substitution
Y Sato, T Yoshino, M Mori
Index: Sato, Yoshihiro; Yoshino, Taro; Mori, Miwako Journal of Organometallic Chemistry, 2005 , vol. 690, # 24-25 p. 5753 - 5758
Full Text: HTML
Citation Number: 33
Abstract
A Pd (0)-catalyzed allylic substitution (ie, Tsuji–Trost reaction) using N-heterocyclic carbene as a ligand was investigated. It has been proven that an imidazolium salt 2d having bulky aromatic rings attached to the nitrogens in its imidazol-2-ylidene skeleton is suitable as a ligand precursor and that a Pd2dba3–imidazolium salt 2d–Cs2CO3 system is highly efficient for producing a Pd–NHC catalyst in this reaction. Allylic substitution using a Pd–NHC ...
Related Articles:
[Ozawa, Fumiyuki; Okamoto, Hideyuki; Kawagishi, Seiji; Yamamoto, Shogo; Minami, Tatsuya; Yoshifuji, Masaaki Journal of the American Chemical Society, 2002 , vol. 124, # 37 p. 10968 - 10969]
[Masuyama, Yoshiro; Nakajima, Yukiko; Okabe, Jun Applied Catalysis A: General, 2010 , vol. 387, # 1-2 p. 107 - 112]
[Fraga, Carlos A.M.; Teixeira, Lis Helena P.; Menezes, Carla Maria De S.; Sant'Anna, Carlos Mauricio R.; Ramos, Maria Da Conceicao K.V.; De Aquino Neto, Francisco R.; Barreiro, Eliezer J. Tetrahedron, 2004 , vol. 60, # 12 p. 2745 - 2755]