Synthesis of Novel S??Bridged Heterotrinuclear Complexes Containing Six??Membered Chelate Rings: Structural, Spectroscopic, and Electrochemical Properties of [Co …
…, Y Miyashita, K Fujisawa, K Okamoto
Index: Amir, Nagina; Motonishi, Masaru; Fujita, Mitsuharu; Miyashita, Yoshitaro; Fujisawa, Kiyoshi; Okamoto, Ken-Ichi European Journal of Inorganic Chemistry, 2006 , # 5 p. 1041 - 1049
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Citation Number: 9
Abstract
Abstract A bidentate ligand, 3-aminopropanethiolate (apt), was synthesized and treated with RhCl 3· 3H 2 O in basic water to yield a novel mononuclear complex, fac (S)-[Rh (apt) 3](1), which was characterized by spectroscopic methods. Furthermore, the reaction of 1 with CoCl 2· 6H 2 O in water formed the linear-type, S-bridged trinuclear complexes ΔΛ-[Co {Rh (apt) 3} 2] 3+(2a) and ΔΔ/ΛΛ-[Co {Rh (apt) 3} 2] 3+(2b), which were characterized by ...
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