Multiple metal-carbon bonds. 41. Wittig-like reactions of tungsten alkylidyne complexes

JH Freudenberger, RR Schrock

Index: Freudenberger, John H.; Schrock, Richard R. Organometallics, 1986 , vol. 5, p. 398 - 400

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Citation Number: 64

Abstract

177.6 (11) 88.7 (9) 95.6 (9) 139.6 (10) 113.7 (13) 127.2 (13) 175.7 (19) 123.0 (15) stituted acylamido ligand. The C (1), 0 (1), N (2), C (2), C (3), and C (7) atoms of the acylamido ligand lie in a plane, but the tungsten atom lies 0.373 (6) A out of this plane. The WN (l) distance (Table I) is comparable to that in other imido complexes. 8 The WO (1) bond is distinctly longer than the WN (2) bond, and the C (1)-00) bond significantly shorter than ...