Transition-state geometries and stereoselectivity of alkylidenecarbene addition to olefins. An experimental and theoretical investigation

Y Apeloig, M Karni, PJ Stang…

Index: Journal of the American Chemical Society, , vol. 105, # 14 p. 4781 - 4792

Full Text: HTML

Citation Number: 69

Abstract

... (1) For reviews and pertinent references see: Kirmse, W. 'Carbene Chemistry”, 2nd 4.; Academic Press: New York, 1971. ... The University of Utah. 0002-7863/83/1505-4781$01.50/0 0 1983 American Chemical Society Page 2. 4782 J. Am. Chem. ... Scheme I Vol. 105, No. 14, 1983 ...

Related Articles:

Organoselenium chemistry. Formation of acetylenes and allenes by syn elimination of vinyl selenoxides

[Journal of the American Chemical Society, , vol. 102, # 18 p. 5967 - 5968]

Reduction of propargylic chlorides with tri-n-butyltin hydride. The ambident behavior of propargylic radicals

[Journal of the American Chemical Society, , vol. 90, p. 5490 - 5498]

The far-ultraviolet photochemistry of alkylcyclopropenes in solution

[Canadian Journal of Chemistry, , vol. 67, p. 1859 - 1867]

Preparation of optically pure propargylic and allylic alcohols from 2-(trimethylsilyl) vinyl sulfoxides as a chiral ethynyl anion synthon: Computational studies on …

[Reich, Hans J.; Willis, William W. Journal of the American Chemical Society, 1980 , vol. 102, # 18 p. 5967 - 5968]

Alkylidenecarbenes from acyclic vinyl bromides and potassium tert-butoxide

[Journal of Organic Chemistry, , vol. 41, p. 745 - 750]

More Articles...