Efficient Manganese/Copper Bimetallic Catalyst for N??Arylation of Amides and Sulfonamides Under Mild Conditions in Water
YC Teo, FF Yong, IK Ithnin, SHT Yio…
Index: Teo, Yong-Chua; Yong, Fui-Fong; Ithnin, Idzham Khalid; Yio, Siew-Hui Trionna; Lin, Zhiyin European Journal of Organic Chemistry, 2013 , # 3 p. 515 - 524
Full Text: HTML
Citation Number: 1
Abstract
Abstract An efficient and mild method using a bimetallic MnF 2/CuI catalyst at 60 C in water was developed for the N-arylation of amides and sulfonamides with aryl halides. A variety of functionalized amides and sulfonamides were coupled with different substituted aryl halides to afford the corresponding N-arylated products in good to excellent yields (up to 97%).
Related Articles:
First enantioselective catalyst for the rearrangement of allylic imidates to allylic amides
[Calter, Michael; Hollis, T. Keith; Overman, Larry E.; Ziller, Joseph; Zipp, G. Greg Journal of Organic Chemistry, 1997 , vol. 62, # 5 p. 1449 - 1456]
[Wang, Jichao; Yin, Xinchi; Wu, Jun; Wu, Datong; Pan, Yuanjiang Tetrahedron, 2013 , vol. 69, # 48 p. 10463 - 10469]
[Crawford, Sarah M.; Lavery, Christopher B.; Stradiotto, Mark Chemistry - A European Journal, 2013 , vol. 19, # 49 p. 16760 - 16771]
A Novel Domino Synthesis of Quinazolinediones by Palladium??Catalyzed Double Carbonylation
[Li, Haoquan; Neumann, Helfried; Beller, Matthias; Wu, Xiao-Feng Angewandte Chemie - International Edition, 2014 , vol. 53, # 12 p. 3183 - 3186 Angew. Chem., 2014 , vol. 126, # 12 p. 3247 - 3250,4]
[Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906]