Journal of the American Chemical Society

The Fluorination of Chlorodisiloxane. Silicon Oxyfluoride1

HS Booth, RA Osten

Index: Booth, H. S.; Osten, R. A. Journal of the American Chemical Society, 1945 , vol. 67, p. 1092 - 1096

Full Text: HTML

Citation Number: 17

Abstract

It has been repeatedly observed in this Laboratory that after boiling off from glass ampules liquefied silicon fluoride small amounts of a white residue which volatilize at about room temperature remain, unless the glass ampules are thoroughly dried by flaming while being rinsed many times with dry air. Partial hydrolysis of silicon tetraftuoride to a volatile oxyfluoride seemed a likely source of the residues. In a study by Glenn McIntyre in this ...

Related Articles:

Etching Silicon with HF–HNO3–H2SO4/H2O Mixtures–Unprecedented Formation of Trifluorosilane, Hexafluorodisiloxane, and Si–F Surface Groups

[Lippold, Marcus; Boehme, Uwe; Gondek, Christoph; Kronstein, Martin; Patzig-Klein, Sebastian; Weser, Martin; Kroke, Edwin European Journal of Inorganic Chemistry, 2012 , # 34 p. 5714 - 5721]

Identification of the products of partial hydrolysis of silicon tetrafluoride by matrix isolation IR spectroscopy

[Sennikov; Ignatov; Schrems Russian Journal of Inorganic Chemistry, 2010 , vol. 55, # 3 p. 413 - 420]

Gas-phase oxidation of vinyltrifluorosilane with nitrogen dioxide under the action of a pulse CO2 laser

[Dement'ev; Koshlyakov; Chesnokov Kinetics and Catalysis, 2010 , vol. 51, # 5 p. 624 - 634]

More Articles...