Metalloporphyrin/Iodine (III)??Cocatalyzed Oxygenation of Aromatic Hydrocarbons

A Yoshimura, HM Neu, VN Nemykin…

Index: Yoshimura, Akira; Neu, Heather M.; Nemykin, Victor N.; Zhdankin, Viktor V. Advanced Synthesis and Catalysis, 2010 , vol. 352, # 9 p. 1455 - 1460

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Citation Number: 17

Abstract

Abstract Hypervalent iodine species have a pronounced catalytic effect on the metalloporphyrin-mediated oxygenations of aromatic hydrocarbons. In particular, the oxidation of anthracene to anthraquinone with Oxone readily occurs at room temperature in aqueous acetonitrile in the presence of 5–20 mol% of iodobenzene and 5 mol% of a water- soluble iron (III)-porphyrin complex. 2-tert-Butylanthracene and phenanthrene also can be ...

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