Organometallics

Carbon-carbon bond-forming reactions of cobaltacyclopentene/cobaltaoxanorbornadiene complexes with isocyanides, carbon monoxide, and alkynes

M Scozzafava, AM Stolzenberg

Index: Scozzafava, Maryrose; Stolzenberg, Alan M. Organometallics, 1988 , vol. 7, p. 1073 - 1083

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Citation Number: 8

Abstract

Reaction of (q5-C5H5) Co [C (R) C (COzCH3) CH (COZCH3) CH (COzCH3)][P (C6H5),](R= CsH5, 2a; R= COZCH3, 2b) with isocyanides, CO, and diphenylacetylene (DPA) afforded l- amino-1, 3-cyclopentadienes, cyclopent-2-enones, and (q5-C5H5) Co (q4-1, 3- cyclohexadiene) complexes, respectively. The related [2.2. 1]-metallabicyclic cobaltaoxanorbornadiene complexes la and lb reacted with the same reagents to afford ...

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