Synthesis, crystal and molecular structure, and reactions of a benzodicobaltacyclohexene, a thermally derived mononuclear o-xylylene complex, and an …

…, FJ Hollander, RG Bergman

Index: Hersh, William H.; Hollander, Frederick J.; Bergman, Robert G. Journal of the American Chemical Society, 1983 , vol. 105, # 18 p. 5834 - 5846

Full Text: HTML

Citation Number: 34

Abstract

Abstract: Alkylation of Na [CpCo (p-CO)],(Cp= ss-cyclopentadienyl) with a, d-dibromo-o- xylene gives bis (pcarbony1)-(po-xylylene) bis [(q5-cyclopentadienyl) cobalt](Co-Co)(l), the first dimetallacyclohexene. The X-ray crystal structure of the derivative analogue 8 having~ 5- methylcyclopentadienyl rings was solved (237 1 reflections; R= 2.64%; space group Pi; a= 9.1045 (I]), b= 9.5465 (13), c= 11.8147 (16) A;(Y= 83.730 (11) O; p= 81.414 (lO) O,= ...

Related Articles:

Organometallic. pi. complexes. XXII. Chemistry of. pi.-cyclopentadienyltetraphenylcyclobutadienecobalt and related compounds

[Rausch, M. D.; Genetti, R. A. Journal of Organic Chemistry, 1970 , vol. 35, p. 3888 - 3897]

Carbon-carbon bond formation in dinuclear dialkyl complexes. Reactions of [CpCo (CO) R] 2 (R= methyl, ethyl, or 2, 2, 2-trifluoroethyl) and (C11H10) Co2 (CO) 2 ( …

[Schore, Neil E.; Ilenda, Casmir S.; White, Mary Ann; Bryndza, Henry E.; Matturro, Michael G.; Bergman, Robert G. Journal of the American Chemical Society, 1984 , vol. 106, # 24 p. 7451 - 7461]

Carbon-carbon bond-forming reactions of cobaltacyclopentene/cobaltaoxanorbornadiene complexes with isocyanides, carbon monoxide, and alkynes

[Scozzafava, Maryrose; Stolzenberg, Alan M. Organometallics, 1988 , vol. 7, p. 1073 - 1083]

Carbon-carbon bond formation in dinuclear dialkyl complexes. Reactions of [CpCo (CO) R] 2 (R= methyl, ethyl, or 2, 2, 2-trifluoroethyl) and (C11H10) Co2 (CO) 2 ( …

[Schore, Neil E.; Ilenda, Casmir S.; White, Mary Ann; Bryndza, Henry E.; Matturro, Michael G.; Bergman, Robert G. Journal of the American Chemical Society, 1984 , vol. 106, # 24 p. 7451 - 7461]

Carbon-carbon bond formation in dinuclear dialkyl complexes. Reactions of [CpCo (CO) R] 2 (R= methyl, ethyl, or 2, 2, 2-trifluoroethyl) and (C11H10) Co2 (CO) 2 ( …

[Journal of the American Chemical Society, , vol. 106, # 24 p. 7451 - 7461]

More Articles...