A Mild Catalytic Oxidation System: Ruthenium Porphyrin and 2, 6??Dichloropyridine N??Oxide Applied for Alkene Dihydroxylation

…, PR Li, G Jiang, CM Che, J Chen

Index: Hu, Wen-Xiang; Li, Pei-Rong; Jiang, Gaoxi; Che, Chi-Ming; Chen, Jian Advanced Synthesis and Catalysis, 2010 , vol. 352, # 18 p. 3190 - 3194

Full Text: HTML

Citation Number: 1

Abstract

Abstract A new method was developed to transform alkenes into three types of functional molecules, including epoxides, aldehydes and 1, 2-diols by using dichlororuthenium (IV) meso-tetrakis (2, 6-dichlorophenyl) porphyrin [Ru (IV)(TDCPP) Cl 2] as catalyst and 2, 6- dichloropyridine N-oxide (Cl 2 pyNO) as the oxidant, in which the 1, 2-diols were afforded via “one-pot” reactions in moderate yields.

Related Articles:

One-pot synthesis of enantiomerically pure 1, 2-diols: asymmetric reduction of aromatic α-oxoaldehydes catalysed by Candida parapsilosis ATCC 7330

[Mahajabeen, Pula; Chadha, Anju Tetrahedron Asymmetry, 2011 , vol. 22, # 24 p. 2156 - 2160]

Chemoenzymatic synthesis of enantiomerically pure 1, 2-diols employing immobilized lipase in the ionic liquid [bmim] PF 6

[Kamal, Ahmed; Chouhan, Gagan Tetrahedron Letters, 2004 , vol. 45, # 48 p. 8801 - 8805]

Ab initio structure determination from x-ray powder diffraction data of tetraaquabismuth (III) triflate obtained from the nonahydrate

[Boisselier, Veronique Le; Dunach, Elisabet; Postel, Michele Journal of Organometallic Chemistry, 1994 , vol. 482, # 1-2 p. 119 - 124]

CuI/l-proline-catalyzed selective one-step mono-acylation of styrenes and stilbenes

[Prathima, P. Sai; Maheswari, C. Uma; Srinivas; Rao, M. Mohan Tetrahedron Letters, 2010 , vol. 51, # 44 p. 5771 - 5774]

Metal-free dihydroxylation of alkenes using cyclobutane malonoyl peroxide

[Jones, Kevin M.; Tomkinson, Nicholas C. O. Journal of Organic Chemistry, 2012 , vol. 77, # 2 p. 921 - 928]

More Articles...