The nature of the sodium dodecylsulfate micellar pseudophase as studied by reaction kinetics
L Onel, NJ Buurma
Index: Onel, Lavinia; Buurma, Niklaas J. Journal of Physical Chemistry B, 2011 , vol. 115, # 45 p. 13199 - 13211
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Citation Number: 18
Abstract
The nature of the rate-retarding effects of anionic micelles of sodium dodecyl sulfate (SDS) on the water-catalyzed hydrolysis of a series of substituted 1-benzoyl-1, 2, 4-triazoles (1a–f) has been studied. We show that medium effects in the micellar Stern region of SDS can be reproduced by simple aqueous model solutions containing small-molecule mimics for the surfactant headgroups and tails, namely sodium methyl sulfate (NMS) and 1-propanol, in ...
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