Palladium-Catalyzed Asymmetric Reduction of Racemic Allylic Esters with Formic Acid: Effects of Phosphine Ligands on Isomerization of π-Allylpalladium …
M Kawatsura, Y Uozumi, M Ogasawara, T Hayashi
Index: Kawatsura, Motoi; Uozumi, Yasuhiro; Ogasawara, Masamichi; Hayashi, Tamio Tetrahedron, 2000 , vol. 56, # 15 p. 2247 - 2257
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Citation Number: 33
Abstract
A new MOP ligand (1b),(R)-(+)-2-(bis (3-trifluoromethylphenyl) phosphino)-2′-methoxy-1, 1′-binaphthyl, was found to be more enantioselective than other MOP ligands for the palladium-catalyzed asymmetric reduction of α, α-disubstituted allylic esters with formic ...
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