Mono-substituted Keggin-polyoxometalate complexes as effective and recyclable catalyst for the oxidation of alcohols with hydrogen peroxide in biphasic system
J Wang, L Yan, G Li, X Wang, Y Ding, J Suo
Index: Wang, Jianmin; Yan, Liang; Li, Guixian; Wang, Xiaolai; Ding, Yong; Suo, Jishuan Tetrahedron Letters, 2005 , vol. 46, # 41 p. 7023 - 7027
Full Text: HTML
Citation Number: 65
Abstract
Mono-substituted Keggin-polyoxymetalate complex Na6 [SiW11ZnH2O40]· 12H2O was demonstrated to be an effective catalyst for the selective oxidation of alcohols in the presence of hydrogen peroxide as oxidant. The reaction was carried out in an aqueous/oil biphasic system, which allowed easy recovery of catalyst, under relative mild conditions. The catalyst could be reused five times without appreciable loss of activity.
Related Articles:
[Doi, Takashi; Fukuyama, Takahide; Minamino, Satoshi; Ryu, Ilhyong Synlett, 2006 , # 18 p. 3013 - 3016]
An unusual dimerization of primary unsaturated alcohols catalyzed by RuHCl (CO)(PPh 3) 3
[Doi, Takashi; Fukuyama, Takahide; Minamino, Satoshi; Husson, Guillaume; Ryu, Ilhyong Chemical Communications, 2006 , # 17 p. 1875 - 1877]
[Ten Brink, Gerd-Jan; Arends, Isabel W. C. E.; Sheldon, Roger A. Advanced Synthesis and Catalysis, 2002 , vol. 344, # 3-4 p. 355 - 369]
The Structure of Ethylketene Dimer
[Wear Journal of the American Chemical Society, 1951 , vol. 73, p. 2390]
The Structure of Ethylketene Dimer
[Wear Journal of the American Chemical Society, 1951 , vol. 73, p. 2390]