Structures and reactions of radical cations of linear alkanes: ESR evidence for selective deprotonation

K Toriyama, K Nunome, M Iwasaki

Index: Toriyama, Kazumi; Nunome, Keichi; Iwasaki, Machio Journal of Physical Chemistry, 1986 , vol. 90, # 26 p. 6836 - 6842

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Citation Number: 76

Abstract

Conclusion Several studies4s5 have reported the observation of the oneelectron reduced form of lumiflavin (FP-or FlH') by flash photolysis in aqueous solution in the absence of added electron donors. Hemmerich and co-workers suggested the formation of F1'-could be accounted for by eq 2. The failure to observe the Fl'+ radical was suggested to be due to either it absorbing at short wavelengths only or its rapid decay via hydrolysis. As we have ...