Journal of Organometallic Chemistry

A convenient synthesis of bromopentaarylcyclopentadienes containing methyl or fluorine substituents

JY Thépot, C Lapinte

Index: Thepot, Jean-Yves; Lapinte, Claude Journal of Organometallic Chemistry, 2001 , vol. 627, # 2 p. 179 - 188

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Citation Number: 12

Abstract

The ketones C5 (3, 5-C6H3Me2) 4 (O)(5b) and C5-2, 5 (3, 5-C6H3Me2) 2 (C6H5) 2 (O)(5c) were prepared and characterized. The pentaarylcyclopentadienols C5 (C6H5) 4 (Ar′)(OH)(Ar′= 3, 5-C6H3Me2, 6a3; Ar′= 2, 4, 6-C6H2Me3, 6a5; Ar′= 3-C6H4F, 6a6; Ar′= 3, 5-C6H3F2, 6a7), C5 (3, 5-C6H3Me2) 4 (Ar′)(OH)(Ar′= 3-C5H4Me, 6b2; 3, 5- C5H3Me2, 6b3; 3, 6-C5H3Me2, 6b4; 2, 4, 6-C5H2Me3, 6b5; Ar′= 3-C6H4F, 6a6; Ar′= 3 ...

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