F??Amphiphilic 1, 2, 3??Triazoles by Unexpected Intramolecular Cyclisation of Vinyl Azides

…, P Lemière, C Gérardin??Charbonnier

Index: Mayot, Estelle; Lemiere, Pascal; Gerardin-Charbonnier, Christine European Journal of Organic Chemistry, 2008 , # 13 p. 2232 - 2239

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Citation Number: 6

Abstract

Abstract A series of fluoroalkylated 1, 2, 3-triazoles have been synthetised in significant yields through unexpected intramolecular cyclisations of vinyl azides bearing electron- withdrawing groups. The mechanism proposed in this study implies the participation of a catalytic amount of azide ions in the cyclisations of the vinyl azides to triazoles. The study includes the alkylation of these compounds with various alkylating agents and the ...