Mechanistic Studies on α-Trifluoromethylation of Ketones via Silyl Enol Ethers and Its Application to Other Carbonyl Compounds
K Sato, T Yuki, R Yamaguchi, T Hamano…
Index: Cantacuzene,D. et al. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1977 , p. 1365 - 1371
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Citation Number: 32
Abstract
... The Journal of Organic ... d ... the α-trifluoromethylation of 1-phenyl-1-trimethylsiloxyethylene (2d) as shown in entry 4 of Table 1. In fact, Mikami's procedure was a radical α-trifluoromethylation of ketones by using Li, Ti, or Zn enolates assisted Et 3 B/O 2 .(13) Furthermore, Chen et al. ...
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