Triethylborane induced perfluoroalkylation of silyl enol ethers or germyl enol ethers with perfluoroalkyl iodides
K Miura, M Taniguchi, K Nozaki, K Oshima, K Utimoto
Index: Miura, Katsukiyo; Taniguchi, Masahiko; Nozaki, Kyoko; Oshima, Koichiro; Utimoto, Kiitiro Tetrahedron Letters, 1990 , vol. 31, # 44 p. 6391 - 6394
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Citation Number: 76
Abstract
Abstract Reaction of perfluoroalkyl iodides with silyl enol ethers mediated by Et 3 B in the presence of a base provides perfluoroalkylated silyl enol ethers. Meanwhile, treatment of germyl enol ethers with perfluoroalkyl iodides affords β-perfluoroalkyl ketones in good yields.
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