Electrochemical oxidation of enamines in the presence of organic anions

T Chiba, M Okimoto, H Nagai…

Index: Chiba,T. et al. Journal of Organic Chemistry, 1979 , vol. 44, p. 3519 - 3523

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Citation Number: 41

Abstract

7 conjugative electron delocalization from N to S will be disfavored. The cyclic dithioamino radicals will therefore have smaller g values and smaller hyperfine splittings by 33S than the acyclic dithioamino radicals (as is observed; see Table 11). In addition, because the cyclic radical is less stabilized than the i~cyclic radical by conjugative electron delocalization, it is more reactive. This provides a simple explanation as to why 3 reacts with oxygen but 5 does not. The ...

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