Generation of a silylethylene-titanium alkoxide complex. a versatile reagent for silylethylation and silylethylidenation of unsaturated compounds

R Mizojiri, H Urabe, F Sato

Index: Mizojiri, Ryo; Urabe, Hirokazu; Sato, Fumie Journal of Organic Chemistry, 2000 , vol. 65, # 19 p. 6217 - 6222

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Citation Number: 41

Abstract

(Trimethylsilyl) ethylene-titanium alkoxide complex (1) was generated from trimethyl (vinyl) silane, Ti (Oi-Pr) 4, and i-PrMgCl as a preformed alkene-titanium complex and reacted with several unsaturated compounds such as aldehyde, imine, other vinylsilane, and acetylene ...