Nickel-catalyzed codimerization of 1, 3-cyclohexadiene and vinyltrimethylsilane. Effects of organophosphorus ligands

P Cros, C Triantaphylides, G Buono

Index: Cros, Philippe; Triantaphylides, Christian; Buono, Gerard Journal of Organic Chemistry, 1988 , vol. 53, # 1 p. 185 - 187

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Citation Number: 14

Abstract

Recent progress achieved by using organosilicon compounds has offered several new aspects to synthetic organic chemistry. l One of them is the use of vinylsilane as a masked carbonyl functionality2 and as a possibility for generation of a-silyl carbanions through the addition of different types of carbanionic species on the activated double bond. 3 Another interesting feature in respect to synthesis results from the electrophilic substitution reaction ...