Rhodium-Catalyzed Direct Oxidative Carbonylation of Aromatic C− H Bond with CO and Alcohols

…, SM Spinella, S Yu, YM Liang, X Zhang

Index: Zhang, Yuhua; Feng, Jianqing; Li, Chao-Jun Journal of the American Chemical Society, 2008 , vol. 130, # 10 p. 2900 - 2901

Full Text: HTML

Citation Number: 91

Abstract

A general protocol for the rhodium-catalyzed oxidative carbonylation of arenes to form esters has been developed. A broad substrate scope has been demonstrated allowing carbonylation of electron-rich, electron-poor, and heterocyclic arenes, and the reaction shows wide functional group tolerance and excellent regioselectivities. Up to 96% yield of ortho-substituted aryl or heteroaryl carboxylic esters were obtained with this methodology. ...

Related Articles:

A New Family of Tunable Indolylphosphine Ligands by One-Pot Assembly and Their Applications in Suzuki− Miyaura Coupling of Aryl Chlorides

[Chau, Ming So; Chung, Chiu Yeung; Chak, Po Lau; Fuk, Yee Kwong Journal of Organic Chemistry, 2008 , vol. 73, # 19 p. 7803 - 7806]

Ruthenium-catalyzed oxidative coupling and cyclization between 2-aminobenzyl alcohol and secondary alcohols leading to quinolines

[Cho, Chan Sik; Kim, Bok Tae; Choi, Heung-Jin; Kim, Tae-Jeong; Shim, Sang Chul Tetrahedron, 2003 , vol. 59, # 40 p. 7997 - 8002]

Rh (I)-Catalyzed Direct Arylation of Azines

[Berman, Ashley M.; Bergman, Robert G.; Ellman, Jonathan A. Journal of Organic Chemistry, 2010 , vol. 75, # 22 p. 7863 - 7868]

Selective reduction of nitroarenes by a Hantzsch 1, 4-dihydropyridine: A facile and efficient approach to substituted quinolines

[Xing, Rui-Guang; Li, Ya-Nan; Liu, Qiang; Han, Yi-Feng; Wei, Xia; Li, Jing; Zhou, Bo Synthesis, 2011 , # 13 p. 2066 - 2072]

Palladium-catalyzed heteroannulation with acetylenic carbinols as synthons-synthesis of quinolines and 2, 3-dihydro-4 (1H)-quinolones

[Mahanty, Jyan S.; De, Mahuya; Das, Palas; Kundu, Nitya G. Tetrahedron, 1997 , vol. 53, # 39 p. 13397 - 13418]

More Articles...