Facile S-alkyl thiocarbamate synthesis by a novel DBU-assisted carbonylation of amines with carbon monoxide and sulfur
T Mizuno, J Takahashi, A Ogawa
Index: Mizuno, Takumi; Takahashi, Junko; Ogawa, Akiya Tetrahedron, 2003 , vol. 59, # 8 p. 1327 - 1331
Full Text: HTML
Citation Number: 32
Abstract
A novel DBU-assisted carbonylation of amines with carbon monoxide and sulfur has been developed for the synthesis of S-alkyl thiocarbamates. In the presence of DBU (1, 8- diazabicyclo [5.4. 0] undec-7-ene), S-alkyl thiocarbamates are synthesized in excellent yields from amines, carbon monoxide, sulfur, and alkyl halides under mild conditions (1atm, 20° C). In the absence of DBU, however, no formation of S-alkyl thiocarbamate is ...
Related Articles:
An improved one-pot cost-effective synthesis of N, N-disubstituted carbamoyl halides and derivatives
[Adeppa; Rupainwar; Misra, Krishna Canadian Journal of Chemistry, 2010 , vol. 88, # 12 p. 1277 - 1280]
[Yuan, Wen; Shang, Zhipei; Qiang, Xiaoming; Tan, Zhenghuai; Deng, Yong Research on Chemical Intermediates, 2014 , vol. 40, # 2 p. 787 - 800]
[Hoshino, Osamu; Saito, Keiji; Ishizaki, Miyuki; Umezawa, Bunsuke Synthetic Communications, 1987 , vol. 17, # 16 p. 1887 - 1892]
Chlorination of Aliphatic Primary Alcohols via Triphosgene–Triethylamine Activation
[Organic Letters, , vol. 14, # 14 p. 3676 - 3679]
[11C] Carbamoyl chlorides: An easy access from [11C] phosgene and tertiary amines
[Journal of Labelled Compounds and Radiopharmaceuticals, , vol. 44, p. S128 - S131]