Stereochemistry of sulfur compounds. II. New reactions at chiral sulfur that complete the first monoligostatic stereochemical reaction cycle

TR Williams, A Nudelman, RE Booms…

Index: Williams,T.R. et al. Journal of the American Chemical Society, 1972 , vol. 94, # 13 p. 4684 - 4691

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Citation Number: 25

Abstract

Abstract: This paper describes several new stereospecific reactions at chiral sulfur, and completion of the first known stereochemical reaction cycle in which only a single ligand is common to all compounds of the reaction cycle (monoligostatic). Additional diligostatic and triligostatic stereochemical reaction cycles are described that involve sulfoxides, sulfimides, sulfoximides, sulfinamides, sulfinamidines, sulfinate, and sulfinimidate esters (compounds ...