… of Phosphanyl Sulfoximines Through Phospha??Michael Reaction of Alkenyl Sulfoximines and Their Evaluation as Chiral Bidentate 1, 5??N, P Ligands for Palladium in …

F Lemasson, HJ Gais, J Runsink…

Index: Lemasson, Fabien; Gais, Hans-Joachim; Runsink, Jan; Raabe, Gerhard European Journal of Organic Chemistry, 2010 , # 11 p. 2157 - 2175

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Citation Number: 8

Abstract

Abstract The intermolecular phospha-Michael reaction of cyclic and acyclic alkenyl sulfoximines proceeds readily and yields the corresponding phosphanyl sulfoximines in good yield. The asymmetric induction provided by sulfoximine group in C–P bond formation is apparently only low. The configuration of three phosphanyl sulfoximine–boranes has been determined by X-ray crystal structure analysis. The ability of the phosphanyl ...