Synthesis of cordiaquinone J and K via B-alkyl Suzuki–Miyaura coupling as a key step and determination of the absolute configuration of natural products
A Yajima, F Saitou, M Sekimoto, S Maetoko, T Nukada…
Index: Yajima, Arata; Saitou, Fumihiro; Sekimoto, Mayu; Maetoko, Shoichiro; Nukada, Tomoo; Yabuta, Goro Tetrahedron, 2005 , vol. 61, # 38 p. 9164 - 9172
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Citation Number: 14
Abstract
A versatile methodology for the synthesis of various terpenoids via B-alkyl Suzuki–Miyaura coupling as a key step is established. Synthesis of cordiaquinone J and K, new antifungal and larvicidal meroterpenoids, was achieved by using this methodology. The absolute configurations of cordiaquinone J and K were confirmed by the synthesis.
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