A kinetic evaluation of carbon-hydrogen, carbon-carbon, and carbon-silicon bond activation in benzylic radical cations
M Freccero, A Pratt, A Albini, C Long
Index: Freccero, Mauro; Pratt, Albert; Albini, Angelo; Long, Conor Journal of the American Chemical Society, 1998 , vol. 120, # 2 p. 284 - 297
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Citation Number: 49
Abstract
A detailed study of the competition between CC, CH, and C-Si bond fragmentation in a series of 4-methoxy-α-substituted toluene radical cations (1+), involving both product studies and kinetic analysis, is presented. CC bond fragmentation occurs with several radical cations in acetonitrile. The rate constants for such processes, determined by laser flash photolysis, varied from 2.8× 104 (1c+) to 1.53× 106 (1f+) s-1. The activation parameters for ...
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