Establishment of the C− NO Bond Dissociation Energy Scale in Solution and Its Application in Analyzing the Trend of NO Transfer from C-Nitroso Compound to Thiols

…, XQ Zhu, X Wang, H Liang, JP Cheng

Index: Li, Xin; Zhu, Xiao-Qing; Zhang, Fan; Wang, Xiao-Xiao; Cheng, Jin-Pei Journal of Organic Chemistry, 2008 , vol. 73, # 6 p. 2428 - 2431

Full Text: HTML

Citation Number: 6

Abstract

The first set of experimentally determined C− NO bond homolytic and heterolytic dissociation enthalpies in solution is derived by using direct titration calorimetry combined with appropriate electrode potentials through thermodynamic cycles. The homolytic bond