On the [3+ 2] Annulation of Cyclic Allylsilanes with N-Phenyltriazolinedione: An Enantio-and Diastereoselective Synthesis of cis-1, 3-Diaminocyclitols

RT Dey, TK Sarkar

Index: Dang, Hai-Shan; Davies, Alwyn G. Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991 , # 12 p. 2011 - 2020

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Citation Number: 8

Abstract

... The Journal of Organic ... side products, eg, the H-ene product 15 and/or the metalla (M)-ene product 16 (Table 1). Indeed, as shown by Davies et al ... Route 1: To a stirred mixture of chloro(2- methoxyphenyl)dimethylsilane (7 g, 34.8 mmol) and Mg turnings (1.5 g, 61.7 mmol) in dry ...