Journal of organometallic chemistry

Cross-coupling reactions between some allyl, homoallyl, and homopropargyl substrates and trialkylalanes or dialkyl-and diaryl-magnesium derivatives

GA Tolstikov, UM Dzhemilev

Index: Tolstikov, G. A.; Dzhemilev, U. M. Journal of Organometallic Chemistry, 1985 , vol. 292, p. 133 - 144

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Citation Number: 6

Abstract

Abstract Trialkylalanes and dialkyl-and diaryl-magnesium derivatives can be cross-coupled with allyl ethers and esters, sulphides, and quaternized allylamines. The reactions proceed uncatalyzed either with mild conditions or in the presence of copper complex catalysts to result in high yields of mono-and di-olefins of various structures.

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