Cross Alkyl–Aryl versus Homo Aryl–Aryl Coupling in Palladium-Catalyzed Coupling of Alkyl–Gold (I) and Aryl–Halide
…, MH Pérez-Temprano, JA Casares, P Espinet
Index: DelPozo, Juan; Casares, Juan A.; Espinet, Pablo Chemical Communications, 2013 , vol. 49, # 65 p. 7246 - 7248
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Citation Number: 5
Abstract
Experiments on palladium-catalyzed cross-coupling of [AuMe (PPh3)] with aryl iodides show that Ar–Ar homocoupling products are the main product or an abundant byproduct of the reaction. The percentage of cross-coupling product is higher for aryls with a larger σp
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