The first used half sandwich ruthenium (II) complexes bearing benzimidazole moiety for N-alkylation of amines with alcohols
S Demir, F Coşkun, İ Özdemir
Index: Demir, Serpil; Coskun, Feyzullah; Oezdemir, Ismail Journal of Organometallic Chemistry, 2014 , vol. 755, p. 134 - 140
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Citation Number: 13
Abstract
Abstract Half sandwich ruthenium (II) complexes were synthesized from [RuCl 2 (η 6-p- cymene)] 2 and N-substituted benzimidazole. All new compounds were characterized by elemental analysis, 1 H NMR, 13 C NMR, and IR spectroscopy. Aminoarenes were readily converted into secondary amines by the reaction at 150 C with benzyl alcohol and in the presence of a catalytic amount of novel ruthenium complexes. All of [RuCl 2 (η 6-p- ...
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