Tetrahedron Letters

Pd-catalyzed coupling of aryl iodides with triarylbismuths as atom-economic multi-coupling organometallic nucleophiles under mild conditions

MLN Rao, D Banerjee, RJ Dhanorkar

Index: Rao, Maddali L.N.; Banerjee, Debasis; Dhanorkar, Ritesh J. Tetrahedron Letters, 2010 , vol. 51, # 47 p. 6101 - 6104

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Citation Number: 18

Abstract

The facile cross-coupling reactivity of triarylbismuth compounds with aryl iodides was achieved under mild heating conditions. The established catalytic protocol using Pd (OAc) 2 (Cy2NH) 2 system exhibited high coupling reactivity with a variety of triarylbismuth and aryl iodide compounds under mild conditions. These coupling reactions were completed in short reaction time affording good to high yields of functionalized biaryl products. The studies of ...

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