Journal of the American Chemical Society

The Relative Reactivities of Chloromethyltrimethylsilane and Chloromethylpentamethyldisiloxane

GF Roedel

Index: Roedel Journal of the American Chemical Society, 1949 , vol. 71, p. 271

Full Text: HTML

Citation Number: 12

Abstract

Summary 1. Thiaxanthenol-5-dioxide and several of its derivatives have been prepared and characterized. 2. The existence of a mobile, two-step oxidation-reduction equilibrium between thiaxanthenol-5-dioxide and thiaxanthone-5-dioxide in alkaline solution has been established. By optical, chemical and electrochemical means it was shown that the colored entity in this equilibrium is a semiquinone.

Related Articles:

Correlation of the specific rates of solvolysis of trimethylsilylmethyl trifluoromethanesulfonate using a two-term Grunwald-Winstein equation

[Kevill, Dennis N.; Goken, Erin G.; Park, Byoung-Chun Journal of Chemical Research, 2006 , # 3 p. 173 - 175]

A novel method for heteroatom-substituted free radical generation by photochemical electron transfer induced desilylation of RXCH2SiMe3 systems

[Brumfield, Martha A.; Quillen, Suzanne L.; Yoon, Ung Chan; Mariano, Patrick S. Journal of the American Chemical Society, 1984 , vol. 106, # 22 p. 6855 - 6856]

Synthesis of Alkoxymethyltrimethylsilanes

[Speier Journal of the American Chemical Society, 1948 , vol. 70, p. 4142]

More Articles...