Synthesis of alkynes and alkynyl iodides bearing a protected amino alcohol moiety as functionalized amino acids precursors

C Ayed, J Picard, N Lubin-Germain, J Uziel…

Index: Ayed, Charfedinne; Picard, Julien; Lubin-Germain, Nadege; Uziel, Jacques; Auge, Jacques Science China Chemistry, 2010 , vol. 53, # 9 p. 1921 - 1926

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Abstract

Abstract Amino acid precursors in protected amino alcohol form are important synthons that can be used as building-blocks for the hemisynthesis of non-natural amino acids. Serine can be used as a common starting material for the synthesis of such compounds differently protected. Particularly, protected amino alcohols bearing an ethynyl and/or an iodoethynyl group can be used in cross-couplings, in 1, 3-dipolar cycloadditions and/or in Nozaki- ...

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