Gas??phase chemistry of dihydromyrcenol with ozone and OH radical: Rate constants and products

CD Forester, JE Ham, JR Wells

Index: Forester, Crystal D.; Ham, Jason E.; Wells International Journal of Chemical Kinetics, 2006 , vol. 38, # 7 p. 451 - 463

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Citation Number: 18

Abstract

Abstract A bimolecular rate constant, k OH+ dihydromyrcenol, of (38±9)× 10− 12 cm 3 molecule− 1 s− 1 was measured using the relative rate technique for the reaction of the hydroxyl radical (OH) with 2, 6-dimethyl-7-octen-2-ol (dihydromyrcenol,) at 297±3 K and 1 atm total pressure. Additionally, an upper limit of the bimolecular rate constant, k math image, of approximately 2× 10− 18 cm 3 molecule− 1 s− 1 was determined by monitoring ...