Visible light induced reactions of nitrogen dioxide with conjugated dienes in a low-temperature argon matrix
N Tanaka, Y Kajii, K Shibuya…
Index: Tanaka, Nobuaki; Kajii, Yoshizumi; Shibuya, Kazuhiko; Nakata, Munetaka Journal of Physical Chemistry, 1993 , vol. 97, # 27 p. 7048 - 7053
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Citation Number: 17
Abstract
Visible light induced oxygen atom transfer from NO2 to conjugated dienes has been investigated in a lowtemperature Ar matrix, where the dienes are 1, 3-butadiene (BD), 2- methyl-l, 3-butadiene (isoprene), and 2, 3-dimethyl-1, 3-butadiene (DMB). In each diene/NOz/Ar system, the corresponding nitrite radical, oxirane, aldehyde, and NO were obtained as the photochemical reaction products. The reactions are initiated by the ...
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