Darstellung und Reaktivität von Phenylthiosubstituierten Oligosilanen
…, B Stadelmann, A Zechmann, P Lassacher…
Index: Uhlig, F.; Stadelmann, B.; Zechmann, A.; Lassacher, P.; Stueger, H.; Hengge, E. Phosphorus, Sulfur and Silicon and the Related Elements, 1994 , vol. 90, # 1-4 p. 29 - 40
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Citation Number: 8
Abstract
Abstract Phenylthio substituted oligosilanes are obtained from the reaction of oligomeric silicon halides with alkali metal thiophenolates M1SPh (MI= Li, Na, K). Si—Si bonds are formed when phenylthiooli-gosilanes are reacted with alkali metal silicon compounds. Alkali metal thiophenolates, the second reaction products can be separated easily. Quite similarly, Fe—Si-bonds are obtained from phenyl-thiosilanes and Na [Fe (CO) 2Cp]. In contrast to ...
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