Facile synthesis of unsymmetrical 1, 1-diaryl-2, 2-difluoroethenes via stepwise coupling of 1, 1-dibromo-2, 2-difluoroethenes
T Fujita, N Suzuki, T Ichitsuka, J Ichikawa
Index: Fujita, Takeshi; Suzuki, Naoto; Ichitsuka, Tomohiro; Ichikawa, Junji Journal of Fluorine Chemistry, 2013 , vol. 155, p. 97 - 101
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Abstract
Abstract Unsymmetrical 1, 1-diaryl-2, 2-difluoroethenes were synthesized from 1, 1-dibromo- 2, 2-difluoroethene, which is commercially available, via the Suzuki–Miyaura coupling in a stepwise fashion. Suitable ligands for each coupling process were used to achieve selective synthesis of these diaryldifluoroethenes.
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