Conjugate Reduction of α, β-Unsaturated Aldehydes with Rhodium (bisoxazolinylphenyl) Catalysts
Y Kanazawa, H Nishiyama
Index: Kanazawa, Yoshinori; Nishiyama, Hisao Synlett, 2006 , # 19 p. 3343 - 3345
Full Text: HTML
Citation Number: 26
Abstract
The catalytic reduction of cinnamaldehyde (3) was carried out using Rh(t-Bu-Phebox)(OAc) 2 (aq) (1) [7] (1 mol%) and (EtO) 2 MeSiH (1.5 equivalents) in a toluene solution at 60 °C (Scheme [1] ). After desilylation, dihydrocinnamaldehyde (4) was obtained in 98% yield, no ...
Related Articles:
Insights into the decomposition of olefin metathesis precatalysts
[Manzini, Simone; Poater, Albert; Nelson, David J.; Cavallo, Luigi; Nolan, Steven P. Chemical Science, 2013 , vol. 5, # 1 p. 180 - 188]
Aryl-fused nitrogen heterocycles by a tandem reduction-Michael addition reaction
[Bunce, Richard A.; Herron, Derrick M.; Ackerman, Matthew L. Journal of Organic Chemistry, 2000 , vol. 65, # 9 p. 2847 - 2850]
Aryl-fused nitrogen heterocycles by a tandem reduction-Michael addition reaction
[Bunce, Richard A.; Herron, Derrick M.; Ackerman, Matthew L. Journal of Organic Chemistry, 2000 , vol. 65, # 9 p. 2847 - 2850]
[Blankespoor, Ronald L.; Smart, Robert P.; Batts, Eric D.; Kiste, Alan A.; Lew, Rebecca E.; Vliet, Marc E. Vander Journal of Organic Chemistry, 1995 , vol. 60, # 21 p. 6852 - 6859]
[Rawat, Varun; Kumar, B. Senthil; Sudalai, Arumugam Organic and Biomolecular Chemistry, 2013 , vol. 11, # 22 p. 3608 - 3611]