A comparison of the reactions of tert-butyl mercury and magnesium chlorides with β-styrenyl derivatives
GA Russell, P Ngoviwatchai
Index: Russell, Glen A.; Ngoviwatchai, Preecha Tetrahedron Letters, 1987 , vol. 28, # 49 p. 6113 - 6116
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Citation Number: 6
Abstract
Tetrahedron Letters,Vol.28,No.49,pp 6113-6116,1987 oo40-4039/87 $3.00 + -00 ... A COMPARISON OF THE REACTIONS OF TBRT-BUML ... Department of Chemistry Iowa State University Ames, Iowa 50011 ... Sumnary: Photostimulated substitution reactions of t-BuHgCl with PhCH=CHQ (Q = I, PhS02, ClHg) proceed by a radical chain. With t-BuMgCl in THF, stereoselectivity excludes this process for Q = I but with Q = PhSOZ (dark or hv) or HgCl (hu), radical ...
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