Reactions of alkylmercurials with heteroatom-centered acceptor radicals
…, HI Tashtoush, A Pla-Dalmau, RK Khanna
Index: Russell, Glen A.; Ngoviwatchai, Preecha; Tashtoush, Hasan I.; Pla-Dalmau, Anna; Khanna, Rajive K. Journal of the American Chemical Society, 1988 , vol. 110, # 11 p. 3530 - 3538
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Citation Number: 76
Abstract
Abstract: The relative reactivities of alkylmercury halides toward PhS, PhSe', or I'decrease drastically from R= tert-butyl to R= sec-alkyl to R= n-butyl, indicative that R'is formed in the rate-determining step in the attack of these radicals upon RHgC1. The alkyl radicals thus formed will enter into chain reactions in which a heteroatom-centered radical (A') is regenerated from substrates such as RS-SR, ArSe-SeAr, ArTe-TeAr, PhSe-S02Ar, Cl- ...
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