An unprecedented rearrangement in collision??induced mass spectrometric fragmentation of protonated benzylamines
J Bialecki, J Ruzicka…
Index: Bialecki, Jason; Ruzicka, Josef; Attygalle, Athula B. Journal of Mass Spectrometry, 2006 , vol. 41, # 9 p. 1195 - 1204
Full Text: HTML
Citation Number: 36
Abstract
Abstract The collision-induced dissociation (CID) mass spectra of several protonated benzylamines are described and mechanistically rationalized. Under collision-induced decomposition conditions, protonated dibenzylamine, for example, loses ammonia, thereby forming an ion of m/z 181. Deuterium labeling experiments confirmed that the additional proton transferred to the nitrogen atom during this loss of ammonia comes from the ortho ...
Related Articles:
[Guthrie, Robert D.; Shi, Buchang Journal of the American Chemical Society, 1990 , vol. 112, # 8 p. 3136 - 3139]
[Hartz, Nikolai; Surya Prakash; Olah, George A. Journal of the American Chemical Society, 1993 , vol. 115, # 3 p. 901 - 905]
Skeletal rearrangements on chemical ionization of dibenzyl ether and derivatives
[Kingston, Eric E.; Shannon, James S.; Diakiw, Vladimir; Lacey, Michael J. Organic Mass Spectrometry, 1981 , vol. 16, # 10 p. 428 - 440]
Skeletal rearrangements on chemical ionization of dibenzyl ether and derivatives
[Kingston, Eric E.; Shannon, James S.; Diakiw, Vladimir; Lacey, Michael J. Organic Mass Spectrometry, 1981 , vol. 16, # 10 p. 428 - 440]