Access to 1, 2, 3, 4-tetraoxygenated benzenes via a double Baeyer–Villiger reaction of quinizarin dimethyl ether: application to the synthesis of bioactive natural …

HL Newson, DA Wild, SY Yeung…

Index: Cook, Amanda K.; Emmert, Marion H.; Sanford, Melanie S. Organic Letters, 2013 , vol. 15, # 21 p. 5428 - 5431

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Abstract

... The Journal of Organic Chemistry. ... hydroxylation(11) (eq 5); and a low-yielding and incompletely regioselective palladium-catalyzed C–H acetoxylation of 1,2 ... figure Scheme 3. Precedents for the Microbial(15) and Chemical(19) Baeyer–Villiger Oxidation of Anthraquinones. In the ...

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