Microwave-assisted solvent-free synthesis of pseudohalophosphates
E Shi, J Xiao, C Pei, J Chen
Index: Shi, Enxue; Xiao, Junhua; Pei, Chengxin; Chen, Jisheng Synthetic Communications, 2011 , vol. 41, # 20 p. 3085 - 3088
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Abstract
Abstract A rapid, efficient, solvent-free, and catalyst-free procedure has been developed for the synthesis of pseudohalophosphates from phosphorochloridate and sodium (or potassium) pseudohalides under microwave irradiation. Diethyl, diisobutyl, and diphenyl phosphorazidates, phosphorocyanidates, and phosphor (isothiocyanidate) s 2a–2i were prepared in good yields under mild conditions.
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