Synthesis

Pseudohalogenation of phosphites

E Shi, C Pei

Index: Shi, Enxue; Pei, Chengxin Synthesis, 2004 , # 18 p. 2995 - 2998

Full Text: HTML

Citation Number: 13

Abstract

Abstract A new type of Atherton-Todd reaction for a convenient pseudohalogenation of phosphites has been developed. Direct azidation, cyanation, and thiocyanation of (RO) 2 P (O) H (R= Et, i-Bu, Ph) were accomplished readily with sodium pseudohalides in acetonitrile

Related Articles:

Reliable protocol for the large scale synthesis of diphenylphosphoryl azide (DPPA)

[Wolff, Oliver; Waldvogel, Siegfried R. Synthesis, 2004 , # 8 p. 1303 - 1305]

Electron demand in the transition state of the cyclopropylidene to allene ring opening

[Warner, Philip; Sutherland, Robert Journal of Organic Chemistry, 1992 , vol. 57, # 23 p. 6294 - 6300]

More Articles...