Modification of the photochemical reactivity of the cyclic ethylene acetal of. alpha.-bromopropiophenone by adsorption within zeolites. A combined contribution of …

A Corma, H Garcia, MA Miranda, J Primo…

Index: Corma, Avelino; Garcia, Hermenegildo; Miranda, Miguel A.; Primo, Jaime; Sabater, Maria J. Journal of Organic Chemistry, 1993 , vol. 58, # 24 p. 6892 - 6894

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Abstract

Irradiation of organic substrates adsorbed on solid surfaces constitutes a general methodology to control the chemical reactivity of excited states and divert the pathways undergone by the reaction intermediates.'Zeolites are useful host materials for this purpose since they fulfill important requirements such as complete photochemical stability, wide range of chemical compositions, and a large diversity of crystalline structures. 2 ...

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