Synthesis and reactions of [(((η 6)-2-acylaryl)-C, O) tetracarbonylmanganese]-tricarbonylchromium complexes: enhancement of diastereoselection during …

…, MR Metzler, G Whitaker, PD Woodgate

Index: Clark, George R.; Metzler, Michael R.; Whitaker, Giles; Woodgate, Paul D. Journal of Organometallic Chemistry, 1996 , vol. 513, # 1-2 p. 109 - 134

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Abstract

Cyclomanganation reactions of [(η6)-acylaryl] tricarbonylchromium complexes have been investigated. Three novel heterobimetallic complexes have been synthesised in moderate to good yield, with one being characterised by X-ray crystallography. Several modes of activating these bimetallic complexes towards coupling reactions with substituted alkenes and alkynes were investigated, including oxidative decarbonylation at room temperature, ...