The formation of 1, 2, 3, 4-tetrafluoronaphthalene in the co-pyrolysis of pentafluorobenzenesulphonyl chloride or pentafluoronitrobenzene with butadiene

…, OI Osina, AM Maksimov, VG Kolechkina

Index: Platonov; Osina; Maksimov; Kolechkina Journal of Fluorine Chemistry, 1999 , vol. 96, # 2 p. 191 - 192

Full Text: HTML

Citation Number: 3

Abstract

1,2,3,4-Tetrafluoronaphthalene (I) was obtained by the thermolysis of tetrafluorobenzobicycloocta[2.2.2]triene (II) 1, 2 and 3. The latter was synthesized by the interaction of tetrafluorobenzyne with benzene 1, 2 and 3. Generation of tetrafluorobenzyne in its turn was realised by the decomposition of pentafluorophenylmagnesium chloride or bromide 1 and 2, as well as pentafluorophenyl lithium [3]. ... In this work, another route to ...