Organophosphorus chemistry. 13 [1]. The Behaviour of 3??Aryliminoxindoles toward Alkyl Phosphites

…, NM Abd El??Rahman, MRH Mahran

Index: Abdou, Wafaa M.; Abd El-Rahman, Naglaa M.; Mahran, Mohamed R. H. Journal fuer Praktische Chemie (Leipzig), 1989 , vol. 331, # 6 p. 906 - 912

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Citation Number: 8

Abstract

Abstract 3-Aryliminoxindoles (6a–c) react with trialkyl phosphites (TAP, 2a–c) only in presence of a protonating agent (H 2 O or CH 3 COOH) to give the respective dialkyl 3- (arylamino-2-oxo-1H-indol-3-yl)-phosphonates (9a–i). Compounds 9 are equally obtained by reacting 6a–c with the appropriate dialkyl phosphite (DAP, 4a–c) in absence of solvent. The role displayed by the arylimine-moiety on the reaction courses is discussed.

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